Hi Uday,
You should be able to convert your data using the description in Help and using a weather file that you download from the NREL NSRDB or one of the sample weather files in the solar_resource folder of your SAM installation.
None of SAM's performance models use precipitable water data, so it does not have a column name in the SAM CSV format description. If you want, you can include the data in your file with any column name. SAM ignores any data in the file that it does not need.
Best regards,
Paul.