Dear Elton,
SAM buys and sells power on an hourly basis. For hours when the renewable energy system generates more electricity than the load (specified on the Electric Load page), SAM sells the excess electricity at the sell rate that applies for that hour (as specified on the Utility Rate page). For hours when the system generates less electricity than the load, SAM buys the extra power necessary to meet the load at the buy rate that applies to that hour.
When you check Enable Net Metering on the Utility Rate page, SAM assumes that the buy and sell rates are the same. You can either model a flat rate that does not change with time, or TOU rates with different rates for different times of day and year. If you clear the Enable Net Metering checkbox, then you can model different buy and sell rates. SAM does not model the monthly or annual accounting that you typically see in actual net metering agreements.
UPDATE: As of SAM 2013.9.20, SAM's net metering model does monthly accounting with rollovers of excess kWh as is typical in most net metering agreements.
Best regards,
Paul.